Π¦Π΅Π½Ρ‚Ρ€Π°Π»ΡŒΠ½ΠΎΡƒΠΊΡ€Π°Ρ—Π½ΡΡŒΠΊΠΈΠΉ Π½Π°ΡƒΠΊΠΎΠ²ΠΈΠΉ вісник. Π’Π΅Ρ…Π½Ρ–Ρ‡Π½Ρ– Π½Π°ΡƒΠΊΠΈ. Випуск 2. - 2019

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    Ѐормування Ρ„Π°Π·ΠΎΠ²ΠΎΠ³ΠΎ складу, структури Ρ‚Π° властивості Π΅Π»Π΅ΠΊΡ‚Ρ€ΠΎΠ΄ΡƒΠ³ΠΎΠ²ΠΈΡ… ΠΏΠΎΠΊΡ€ΠΈΡ‚Ρ‚Ρ–Π² систСми Fe-Mn-Nb-Si-C для зміцнСння Ρ€ΠΎΠ±ΠΎΡ‡ΠΈΡ… ΠΏΠΎΠ²Π΅Ρ€Ρ…ΠΎΠ½ΡŒ Π·Π΅ΠΌΠ»Π΅Ρ€ΠΈΠΉΠ½ΠΎΡ— Ρ‚Π΅Ρ…Π½Ρ–ΠΊΠΈ
    (ЦНВУ, 2019) ΠŸΡ€ΠΈΡΡΠΆΠ½ΡŽΠΊ, П. М.; ΠΠ½Π΄Ρ€ΡƒΡΠΈΡˆΠΈΠ½, Π . Π’.; Π›ΡƒΡ†Π°ΠΊ, Π›. Π”.; Π†Π²Π°Π½ΠΎΠ², О. О.; ΠΠ½Π΄Ρ€ΡƒΡΡ‹ΡˆΠΈΠ½, Π . Π’.; Иванов, А. А.; Prysyazhnyuk, P.; Andrusyshyn, R.; Lutsak, L.; Ivanov, O.
    Для ΠΏΠΎΡ€ΠΎΡˆΠΊΠΎΠ²ΠΈΡ… Π΅Π»Π΅ΠΊΡ‚Ρ€ΠΎΠ΄Π½ΠΈΡ… ΠΌΠ°Ρ‚Π΅Ρ€Ρ–Π°Π»Ρ–Π² Ρ–Π· ΠΏΠΎΠ·ΠΈΡ†Ρ–Ρ— Ρ€Ρ–Π²Π½ΠΎΠ²Π°ΠΆΠ½ΠΎΡ— Ρ‚Π΅Ρ€ΠΌΠΎΠ΄ΠΈΠ½Π°ΠΌΡ–ΠΊΠΈ розглянуто систСму лСгування Fe-Mn-Nb-Si-C. Π ΠΎΠ·Ρ€Π°Ρ…ΠΎΠ²Π°Π½ΠΎ Ρ€Ρ–Π²Π½ΠΎΠ²Π°ΠΆΠ½ΠΈΠΉ Ρ„Π°Π·ΠΎΠ²ΠΈΠΉ склад систСм Ρ…Π°Ρ€Π°ΠΊΡ‚Π΅Ρ€Π½ΠΈΠΉ для ΠΌΠ°Ρ‚Π΅Ρ€Ρ–Π°Π»Ρ–Π², Ρ‰ΠΎ Π²Ρ–Π΄ΠΏΠΎΠ²Ρ–Π΄Π°ΡŽΡ‚ΡŒ високомарганцСвим Π΅Π»Π΅ΠΊΡ‚Ρ€ΠΎΠ΄Π°ΠΌ Π»Π΅Π³ΠΎΠ²Π°Π½ΠΈΠΌ ΠΊΠ°Ρ€Π±Ρ–Π΄ΠΎΠΌ Π½Ρ–ΠΎΠ±Ρ–ΡŽ. Показано, Ρ‰ΠΎ Ρƒ процСсі кристалізації ΠΌΠ΅Ρ‚Π°Π»Ρƒ, Π½Π°ΠΏΠ»Π°Π²Π»Π΅Π½ΠΎΠ³ΠΎ Ρ‚Π°ΠΊΠΈΠΌΠΈ Π΅Π»Π΅ΠΊΡ‚Ρ€ΠΎΠ΄Π½ΠΈΠΌΠΈ ΠΌΠ°Ρ‚Π΅Ρ€Ρ–Π°Π»Π°ΠΌΠΈ Ρ€Ρ–Π²Π½ΠΎΠ²Π°ΠΆΠ½ΠΎΡŽ Ρ” аустСніто-ΠΊΠ°Ρ€Π±Ρ–Π΄Π½Π° структура. Π•ΠΊΡΠΏΠ΅Ρ€ΠΈΠΌΠ΅Π½Ρ‚Π°Π»ΡŒΠ½Ρ– дослідТСння структури Π½Π°ΠΏΠ»Π°Π²Π»Π΅Π½ΠΈΡ… ΠΏΡ–Π΄Ρ‚Π²Π΅Ρ€Π΄ΠΆΡƒΡŽΡ‚ΡŒ Ρ€Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚ΠΈ Ρ€ΠΎΠ·Ρ€Π°Ρ…ΡƒΠ½ΠΊΡ–Π². Π—Π°ΠΏΡ€ΠΎΠΏΠΎΠ½ΠΎΠ²Π°Π½Π° систСма лСгування дозволяє ΠΎΡ‚Ρ€ΠΈΠΌΠ°Ρ‚ΠΈ Ρ‚Π²Π΅Ρ€Π΄Ρ–ΡΡ‚ΡŒ ΠΏΠΎΠ²Π΅Ρ€Ρ…Π½Π΅Π²ΠΎΠ³ΠΎ ΡˆΠ°Ρ€Ρƒ Π½Π° Ρ€Ρ–Π²Π½Ρ– 35 HRC після наплавлСння Ρ‚Π° 54 HRC після пластичної Π΄Π΅Ρ„ΠΎΡ€ΠΌΠ°Ρ†Ρ–Ρ—. Для ΠΏΠΎΡ€ΠΎΡˆΠΊΠΎΠ²Ρ‹Ρ… элСктродных ΠΌΠ°Ρ‚Π΅Ρ€ΠΈΠ°Π»ΠΎΠ² с ΠΏΠΎΠ·ΠΈΡ†ΠΈΠΈ равновСсной Ρ‚Π΅Ρ€ΠΌΠΎΠ΄ΠΈΠ½Π°ΠΌΠΈΠΊΠΈ рассмотрСна систСма лСгирования Fe-Mn-Nb-Si-C. Рассчитан равновСсный Ρ„Π°Π·ΠΎΠ²Ρ‹ΠΉ состав систСм, ΠΊΠΎΡ‚ΠΎΡ€Ρ‹ΠΉ Ρ…Π°Ρ€Π°ΠΊΡ‚Π΅Ρ€Π΅Π½ для ΠΌΠ°Ρ‚Π΅Ρ€ΠΈΠ°Π»ΠΎΠ², ΠΊΠΎΡ‚ΠΎΡ€Ρ‹Π΅ ΡΠΎΠΎΡ‚Π²Π΅Ρ‚ΡΡ‚Π²ΡƒΡŽΡ‚ высокомарганцСвым элСктродам Π»Π΅Π³ΠΈΡ€ΠΎΠ²Π°Π½Π½Ρ‹ΠΌ ΠΊΠ°Ρ€Π±ΠΈΠ΄ΠΎΠΌ ниобия. Показано, Ρ‡Ρ‚ΠΎ Π² процСссС кристаллизации ΠΌΠ΅Ρ‚Π°Π»Π»Π°, Π½Π°ΠΏΠ»Π°Π²Π»Π΅Π½Π½ΠΎΠ³ΠΎ Ρ‚Π°ΠΊΠΈΠΌΠΈ элСктродными ΠΌΠ°Ρ‚Π΅Ρ€ΠΈΠ°Π»Π°ΠΌΠΈ равновСсной являСтся аустСнито-карбидная структура. Π­ΠΊΡΠΏΠ΅Ρ€ΠΈΠΌΠ΅Π½Ρ‚Π°Π»ΡŒΠ½Ρ‹Π΅ исслСдования структуры Π½Π°ΠΏΠ»Π°Π²Π»Π΅Π½Π½Ρ‹Ρ… ΠΏΠΎΠ΄Ρ‚Π²Π΅Ρ€ΠΆΠ΄Π°ΡŽΡ‚ Ρ€Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Ρ‹ расчСтов. ΠŸΡ€Π΅Π΄Π»ΠΎΠΆΠ΅Π½Π½Π°Ρ систСма лСгирования позволяСт ΠΏΠΎΠ»ΡƒΡ‡ΠΈΡ‚ΡŒ Ρ‚Π²Π΅Ρ€Π΄ΠΎΡΡ‚ΡŒ повСрхностного слоя Π½Π° ΡƒΡ€ΠΎΠ²Π½Π΅ 35 HRC послС Π½Π°ΠΏΠ»Π°Π²ΠΊΠΈ ΠΈ 54 HRC послС пластичСской Π΄Π΅Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠΈ. The purpose of the study was to establish the regularities of formation of the structure, phase composition and properties of electric arc coatings of powder wires based on high-alloy (manganese) steel with niobioum carbide additions using CALPHAD method together with expiremental investigation of structure and properties and obtainig the hardfacing material with high impact arbasive wear resistance for earth moving machines equipment. Using the free energy calculations of a multicomponent system by the Calpad method, a pseudobinary phase diagram of a highmanganese steel - niobium carbide system was constructed. The use of the diagram made it possible to predict the phase and elemental composition of electric arc coatings made of powder electrode materials. The proposed alloying system allows to obtain a surface layer consisting of two phases: manganese austenite and niobium carbide in the form of dispersed inclusions. The results of measuring the hardness of the arc coatings of the proposed doping system show that increasing the content of niobium carbide in high manganese hardfacing alloy from 0 to 10 vol. % leads to an increase in the hardness of the surface layer from 20 to 35 HRC in the undeformed state and from 46 to 54 in the deformed state. The results show that the presence of disperse NbC inclusions in the amount of more than 6 % by volume increases the intensity of hardening of the surface layer during deformation due to the formation of microregions with high level of internal stresses. According to the results of theoretical and experimental researches, a system of doping of powder electrode materials was developed to strengthen the working bodies of earthmoving equipment, which operates under conditions of considerable dynamic loads in abrasive media. It is established that when alloying electrode materials based on manganese steels close in composition to 110G13L steel, niobium carbide significantly increases both the initial hardness (before deformation) and the hardness after deformation. The obtained value of the hardness of the deformed layer - 54 HRC significantly exceeds the hardness of the serial high-manganese alloys (46 HRC) hardfacings.